| BRAZILIAN HEADS OF MISSION AMBASSADORS AND MINISTERS PLENIPOTENTIARY 1823 - 2010 |
|
| incumbent | Ambassador Roberto Jaguaribe |
| 2008 - 2010 | Ambassador Carlos Augusto R. Santos-Neves |
| 2003 - 2008 | Ambassador José Maurício de Figueiredo Bustani |
| 2001 - 2002 | Ambassador Celso Luiz Nunes Amorim |
| 1999 - 2001 | Ambassador Sérgio Silva Amaral |
| 1994 - 1999 | Ambassador Rubens Antonio Barbosa |
| 1990 - 1993 | Ambassador Paulo Tarso Flecha de Lima |
| 1986 - 1989 | Ambassador Celso de Souza e Silva |
| 1982 - 1986 | Ambassador Mario Gibson Alves Barboza |
| 1975 - 1982 | Ambassador Roberto Campos |
| 1968 - 1974 | Ambassador Sérgio Corrêa Affonso da Costa |
| 1966 - 1968 | Ambassador Jayme Sloan Chermont |
| 1964 - 1966 | Ambassador Carlos Alves de Souza |
| 1961 - 1963 | Ambassador José Cochrane de Alencar |
| 1957 - 1961 | Ambassador Francisco de Assis Chateaubriand de Mello |
| 1952 - 1956 | Ambassador Samuel de Souza-Leão Gracie |
| 1940 - 1952 | Ambassador João Joaquim de Lima e Silva Moniz de Aragão |
| 1925 - 1937 | Ambassador Raul Régis de Oliveira |
| 1920 - 1924 | Ambassador Domício da Gama * |
| 1914 - 1920 ** | Minister Antonio Fontoura Xavier |
| 1913 - 1914 | Minister Plenipotentiary Eduardo Lisboa |
| 1905 - 1913 | Minister Plenipotentiary Dr Francisco Régis de Oliveira |
| 1900 | Minister Plenipotentiary Dr Joaquim Nabuco |
| 1890 - 1900 | Minister Plenipotentiary João Arthur Souza Corrêa |
| 1873 - 1889 | Minister Plenipotentiary Francisco Ignácio de Carvalho Moreira, Baron of Penedo |
| 1868 - 1873 | Minister Plenipotentiary José Carlos de Almeida Arêas, Viscount of Ourem |
| 1866 - 1867 | Minister Plenipotentiary Francisco Ignácio de Carvalho Moreira |
| 1855 - 1863 | Minister Plenipotentiary Francisco Ignácio de Carvalho Moreira |
| 1851 - 1854 | Minister Plenipotentiary Sergio Teixeira de Macedo |
| 1841 | Minister Plenipotentiary José Marques Lisboa |
| 1840 | Minister Plenipotentiary Francisco Gê Acayaba de Montezuma, Viscount of Jequitinhonha |
| 1835 | Minister Plenipotentiary Manoel Antonio Galvão |
| 1831 | Minister Plenipotentiary José Araujo Ribeiro, Viscount of Rio Grande |
| 1825 | Minister Plenipotentiary Manoel Rodrigues Gameiro Pessoa |
| 1824 | Minister Plenipotentiary Felisberto Caldeira Brant Pontes, Marquess of Barbacena |
| 1823 | Minister Plenipotentiary Manoel Rodrigues Gameiro Pessoa, Viscount of Itabaiana |
* Domício da Gama was the first Brazilian ambassador to the UK
** On 2 January 1919 the Brazilian legation in London became the Embassy of Brazil in London